Welcome to the forums! Ideally you replace the door. You could push in the rough areas and use a filler like Durham's Rock Hard Putty to fill the hole and the try and replicate the finish texture. I doubt you can patch it and make the repair disappear but you can make it not as noticeable.
It will only be semi-permanent. It's a bedroom window, so many years from now, when the house is sold, it will need to be there. I think the heat will be able to dissipate, since the hardboard is not right up against the interior wall, but spaced out at least an inch and a half. One possibility to reduce incoming heat would be to cover the window on the outside with louvered white shutters.
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